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Published equation contexts

D=RTN⋅16πkPD = \frac{RT}{N}\cdot\frac{1}{6\pi k P}

Why this formula appears here

with the diffusion constant D fixed by measurable quantities. Einstein derived it explicitly, from the balance between the drag on a sphere of radius P in a fluid of viscosity k and the osmotic pressure driving diffusion, as D=RTN⋅16πkPD = \frac{RT}{N}\cdot\frac{1}{6\pi k P}. where R is the gas constant, T the absolute temperature, and N Avogadro’s number [ 1 ] . That last dependency was the trap door: if D could be read off a microscope by timing how far a particle wandered, and every other term in the equation was already known independently, then watching one particle jiggle became a way to count atoms.

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NN

Symbol N

N occurs below the fraction bar. The quantity above the bar is divided by this expression; zero is excluded as a denominator.

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π\pi

Symbol pi

pi occurs below the fraction bar. The quantity above the bar is divided by this expression; zero is excluded as a denominator.

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kk

Symbol k

k occurs below the fraction bar. The quantity above the bar is divided by this expression; zero is excluded as a denominator.

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How to interpret it

With a fixed numerator, increasing a nonzero denominator reduces the fraction. Read it with the definitions, units, and assumptions supplied by the article.

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Published contexts (1)

A symbol can carry a different meaning in another article. Each occurrence keeps its own guide and term definitions.

D=RTN⋅16πkP,D = \frac{RT}{N}\cdot\frac{1}{6\pi k P},

Equation 7 · Einstein & Evolution

Einstein's Random Walk and the Mathematics of Genetic Drift

This equation states an equality: the expressions on both sides have the same value under the article’s assumptions.

with the diffusion constant D fixed by measurable quantities. Einstein derived it explicitly, from the balance between the drag on a sphere of radius P in a fluid of viscosity k and the osmotic pressure driving diffusion, as D=RTN⋅16πkPD = \frac{RT}{N}\cdot\frac{1}{6\pi k P}. where R is the gas constant, T the absolute temperature, and N Avogadro’s number [ 1 ] . That last dependency was the trap door: if D could be read off a microscope by timing how far a particle wandered, and every other term in the equation was already known independently, then watching one particle jiggle became a way to count atoms.

Meanings in this article

  • RR: the gas constant.
  • TT: the absolute temperature.
  • PP: the radius.
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