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Equation 17 · The Arrow of Time and the Engine of Evolution

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e(W−ΔF)/kBTe^{(W-\Delta F)/k_{\mathrm B}T}

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e(W−ΔF)/kBTe^{(W-\Delta F)/k_{\mathrm B}T}

Symbol e^(W-Δ F)/k_mathrm BT

e^(W-Δ F)/kmk_mathrm BT is a part of this expression. Its role is fixed by the surrounding article and by the operations shown in the formula.

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subtraction

subtraction

Subtract the following term or group from the preceding one. A leading minus marks a negative quantity.

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change

change

Capital delta attached to a quantity marks a difference between two values of that quantity; the article’s sign convention determines the order.

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subscript

subscript

The lower label selects a particular version, component, or indexed member of the quantity. For example, x₀ and xₜ can be values at different positions.

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superscript

superscript

A raised number can be a power. When it is a label or bound, it selects a case or the upper limit of a sum; the formula’s structure distinguishes these uses.

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What the article says around this equation

[ 6 ] . Where W exactly equals Δ\Delta F , the ratio is one and the forward distribution crosses the reflected reverse distribution; away from that point, the ratio grows exponentially in how far W departs from Δ\Delta F , which is the precise, quantitative sense in which a trajectory doing much more work than the equilibrium minimum is exponentially more typical of the forward process than of its reverse. This is the arrow of time rendered as an odds ratio rather than an inequality: not “entropy increases,” but “this particular trajectory is e(W−ΔF)/kBTe^{(W-\Delta F)/k_{\mathrm B}T} times more likely to have been produced running forward than running backward.”

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