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Equation 12 · Part 9 · The Arrow of Time and the Engine of Evolution

subtraction

PF(+W)PR(−W)=exp⁡ ⁣(W−ΔFkBT)\frac{P_{\mathrm F}(+W)}{P_{\mathrm R}(-W)} = \exp\!\left(\frac{W - \Delta F}{k_{\mathrm{B}} T}\right)
subtraction

What this part means

Subtract the following term or group from the preceding one. A leading minus marks a negative quantity.

Its job in the formula

Subtract the following term or group from the preceding one. A leading minus marks a negative quantity.

The passage around this formula

Gavin Crooks sharpened this two years later into a statement about entire probability distributions rather than a single average. If PF(W)P_{\mathrm F}(W) is the distribution of work values measured over many repetitions of a forward protocol, and PR(W)P_{\mathrm R}(W) is the distribution measured over the time-reversed protocol run from its own correctly defined reverse-equilibrium starting ensemble, the two distributions are related by PF(+W)PR(−W)=exp⁡ ⁣(W−ΔFkBT)\frac{P_{\mathrm F}(+W)}{P_{\mathrm R}(-W)} = \exp\!\left(\frac{W - \Delta F}{k_{\mathrm{B}} T}\right). [ 6 ] . Where W exactly equals Δ\Delta F , the ratio is one and the forward distribution crosses the reflected reverse distribution; away from that point, the ratio grows exponentially in how far W departs from Δ\Delta F , which is the precise,…

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Learn the underlying idea

Addition combines quantities; subtraction measures the signed difference between them. Parentheses show what is combined before the rest of the expression is evaluated.

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Sources cited in the surrounding passage

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