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ssys(t)=−kBln⁡p(xt,t)s_{\mathrm{sys}}(t) = -k_{\mathrm B}\ln p(x_t,t)

Why this formula appears here

The system’s stochastic entropy is defined from the ensemble density evaluated at the realized state, ssys(t)=−kBln⁡p(xt,t)s_{\mathrm{sys}}(t) = -k_{\mathrm B}\ln p(x_t,t). For a single thermal bath, the medium entropy change is related to dissipated heat, subject to sign convention, and total entropy combines system and medium contributions. This allows every observed path to receive a thermodynamic accounting while preserving the distinction between a random trajectory-level quantity and its ensemble expectation [ 4 ] .

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ssyss_{\mathrm{sys}}

Symbol s_sys

sss_sys is part of the quantity the equation computes from the expression on the right.

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kBk_{\mathrm B}

Symbol k_mathrm B

kmk_mathrm B is one of the signed contributions combined to compute the quantity on the left.

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Published contexts (1)

A symbol can carry a different meaning in another article. Each occurrence keeps its own guide and term definitions.

ssys(t)=−kBln⁡p(xt,t).s_{\mathrm{sys}}(t) = -k_{\mathrm B}\ln p(x_t,t).

Equation 18 · Physics

The Statistical Mechanics of Irreversibility at Molecular Scale

This equation states an equality: the expressions on both sides have the same value under the article’s assumptions.

The system’s stochastic entropy is defined from the ensemble density evaluated at the realized state, ssys(t)=−kBln⁡p(xt,t)s_{\mathrm{sys}}(t) = -k_{\mathrm B}\ln p(x_t,t). For a single thermal bath, the medium entropy change is related to dissipated heat, subject to sign convention, and total entropy combines system and medium contributions. This allows every observed path to receive a thermodynamic accounting while preserving the distinction between a random trajectory-level quantity and its ensemble expectation [ 4 ] .

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