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SF=ξi/∑jξjS_F = \xi_i / \sum_j \xi_j

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When a reaction can plausibly form more than one product — partial versus complete oxidation, a straight-chain versus branched hydrocarbon, hydrogen versus oxygen evolution as a side reaction — “selectivity” names which pathway wins, and IUPAC defines it with no vocabulary that presumes anything about the catalyst’s intent: fractional selectivity for a given product is the extent-of-reaction rate toward that product divided by the sum of rates toward all products, SFS_F = ξi\xi_i / ∑j\sum_j ξj\xi_j , and relative selectivity between two products is simply the ratio of their two rates [ 2 ] . Selectivity is therefore a kinetic competition among simultaneous pathways, decided by which transition state…

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jj

Symbol j

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jj

Starting index or lower bound: j

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SF=ξi/∑jξjS_F = \xi_i / \sum_j \xi_j

Equation 3 · Chemistry

How Chemical Dynamics and Catalysis Actually Work

This equation states an equality: the expressions on both sides have the same value under the article’s assumptions.

When a reaction can plausibly form more than one product — partial versus complete oxidation, a straight-chain versus branched hydrocarbon, hydrogen versus oxygen evolution as a side reaction — “selectivity” names which pathway wins, and IUPAC defines it with no vocabulary that presumes anything about the catalyst’s intent: fractional selectivity for a given product is the extent-of-reaction rate toward that product divided by the sum of rates toward all products, SFS_F = ξi\xi_i / ∑j\sum_j ξj\xi_j , and relative selectivity between two products is simply the ratio of their two rates [ 2 ] . Selectivity is therefore a kinetic competition among simultaneous pathways, decided by which transition state…

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