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Equation 21 · Part 1 · The Statistical Mechanics of Irreversibility at Molecular Scale

Symbol Sigma_τ

⟨Στ⟩=⟨Δstot⟩/kB\langle\Sigma_\tau\rangle=\langle\Delta s_{\mathrm{tot}}\rangle/k_{\mathrm B}
Στ\Sigma_\tau

What this part means

Sigma_τ is part of the quantity the equation computes from the expression on the right.

Its job in the formula

Sigma_τ is part of the quantity the equation computes from the expression on the right.

The passage around this formula

A molecular clock or motor is useful not only when its average current is nonzero but when that current is sufficiently precise. Let JτJ_\tau be an integrated current observed for time τ\tau , such as net molecular steps or transported ions. Define dimensionless mean entropy production ⟨\langleΣτ\Sigma_\tau⟩\rangle=⟨\langleΔ\Delta stots_{\mathrm{tot}}⟩\rangle/kBk_{\mathrm B} . A canonical steady-state thermodynamic uncertainty relation has the form

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