← All parts of this equation

Equation 14 · Part 2 · The Statistical Mechanics of Irreversibility at Molecular Scale

Symbol W

PF(W)PR(−W)=exp⁡[β(W−ΔF)].\frac{P_{\mathrm F}(W)}{P_{\mathrm R}(-W)} = \exp\left[\beta(W-\Delta F)\right].
WW

What this part means

W is an argument of the function-like quantity on the left; its role is set by that function’s stated inputs.

Its job in the formula

W is an argument of the function-like quantity on the left; its role is set by that function’s stated inputs.

The passage around this formula

Crooks sharpened the connection by comparing complete forward and reverse work distributions [ 3 ] : PF(W)PR(−W)=exp⁡[β(W−ΔF)]\frac{P_{\mathrm F}(W)}{P_{\mathrm R}(-W)} = \exp\left[\beta(W-\Delta F)\right]. At W=Δ\Delta F , the ratio equals one, so the forward distribution and the reflected reverse distribution cross. This provides both a geometric interpretation and an experimental route to free-energy differences.

Read this part in the article →

Learn the underlying idea

A variable is a named place for a value. Its letter is a local label: x can mean position in one formula and a data point in another.

Open the illustrated variables: a letter stands for a value guide →

See this notation across published equations →

Sources cited in the surrounding passage

These citations provide research context; check each source for the exact claim it supports.