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Equation 3 · Part 1 · How Stochastic Thermodynamics and Complex Systems Actually Work

Symbol W

WW
WW

What this part means

W is a part of this expression. Its role is fixed by the surrounding article and by the operations shown in the formula.

Its job in the formula

W is a part of this expression. Its role is fixed by the surrounding article and by the operations shown in the formula.

The passage around this formula

where the average is taken over the distribution of work values W from repeated nonequilibrium pulls, kBk_B is Boltzmann’s constant and T the bath temperature [ 1 ] . The identity holds regardless of how fast or violent the pulling protocol is, provided the system starts each repetition in thermal equilibrium. This is the mechanism, stated plainly: because the exponential average is dominated by the rare trajectories that violate the second law locally by absorbing more work back than expected, those rare low-work outcomes carry disproportionate weight, and that weighting is exactly what reconstructs the equilibrium quantity from an ensemble of nonequilibrium runs.

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A variable is a named place for a value. Its letter is a local label: x can mean position in one formula and a data point in another.

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Sources cited in the surrounding passage

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